Antonio Rudiger's last-minute header shattered Shakhtar Donetsk hearts in Warsaw, with a 1-1 draw securing Real Madrid's spot in the Champions League knockout stages.
Oleksandr Zubkov opened the scoring a minute into the second half to put the Ukrainian side in sight of a sensational result on Tuesday, with the hosts close to doubling their lead when Lassina Traore clipped the crossbar.
Juventus' hopes of progressing to the Champions League last 16 suffered a massive blow as they were stunned 2-0 by Maccabi Haifa.
The Bianconeri went into their third Group H encounter trailing pacesetters Paris Saint-Germain and Benfica by four points.
Chelsea claimed their first Champions League win in Italy for 19 years by defeating 10-man Milan 2-0 at San Siro to move to the top of Group E.
A 4-0 victory over Lazio in November 2003 had represented the Blues' last win on Italian soil in Europe's elite club competition, but this was similarly routine following a contentious Fikayo Tomori red card.
Jurgen Klopp and Diogo Jota have been encouraged by Darwin Nunez's displays ahead Liverpool's Champions League meeting with Rangers.
Nunez struggled to hit the ground running at Liverpool following his arrival from Benfica and has only featured in five Premier League matches – for a total of 267 minutes – due in large part to a three-game suspension he received for lashing out at Crystal Palace's Joachim Andersen in August.
Xavi warned Barcelona they have "no margin for error" in Wednesday's Champions League meeting with Inter, declaring only a win will do for the Blaugrana at Camp Nou.
Hakan Calhanoglu's long-range strike condemned Barca to their second defeat in three Champions League outings last week, leaving them three points adrift of the Nerazzurri in Group C.
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